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标题:ThermoresponsiveCharacteristicsofFluoroalkylEnd-CappedCo-oligomersinAqueousSolutio...
标题:Thermoresponsive Characteristics of Fluoroalkyl End-Capped Co-oligomers in Aqueous Solutions and on the Poly(methyl
methacrylate) Film Surface
Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide - acryloylmorpholine co-oligomers were prepared by the co-oligomerizations of fluoroalkanoyl peroxides with the corresponding monomers. These fluorinated co-oligomers exhibited a lower critical solution temperature (LCST) characteristic in aqueous solutions. Of particular interest, a steep time dependence of contact angle values for dodecane was observed from 40 to 60 °C to decrease their values, effectively, on the modified PMMA [poly(methyl methacrylate)] film surface treated with fluorinated co-oligomer possessing the LCST: 36 °C (in water), although such a steep time dependence was not observed from 20 to 30 °C. 展开
methacrylate) Film Surface
Fluoroalkyl end-capped N-(1,1-dimethyl-3-oxobutyl)acrylamide - acryloylmorpholine co-oligomers were prepared by the co-oligomerizations of fluoroalkanoyl peroxides with the corresponding monomers. These fluorinated co-oligomers exhibited a lower critical solution temperature (LCST) characteristic in aqueous solutions. Of particular interest, a steep time dependence of contact angle values for dodecane was observed from 40 to 60 °C to decrease their values, effectively, on the modified PMMA [poly(methyl methacrylate)] film surface treated with fluorinated co-oligomer possessing the LCST: 36 °C (in water), although such a steep time dependence was not observed from 20 to 30 °C. 展开
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