已知氢氧化镁的ksp=1.8·10^-11,则氢氧化镁的饱和溶液的ph是多少
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解析:
Ksp(Mg(OH)2)= 1.8×10^(-11)
Ksp(Mg(OH)2)= c(<Mg>2+)× [ c(<OH>-)] ^2
饱和溶液中 c(<OH>-)= c(<Mg>2+)× 2
所以
Ksp(Mg(OH)2)= c(<Mg>2+)× [ c(<OH>-)] ^2
= 1/2 × c(<OH>-)× [ c(<OH>-)] ^2
= 1/2 × [ c(<OH>-)] ^3
解得:[ c(<OH>-)] = (2 × Ksp )^(1/3)
= [ 2 × 1.8×10^(-11)]^(1/3)
= 7.11379 ×10^(-3)mol/L
室温时,c(<OH>-)× c(<H3O>+)= 10^(-14)
则 c(<H3O>+)= 10^(-14)/ c(<OH>-)
= 10^(-14)/ 7.11379 ×10^(-3)
= 1.4057211×10^(-10) mol/L
pH = - lg [ <H3O>+ ] = - lg [ 1.4057211×10^(-10) ] = 9.8521
Ksp(Mg(OH)2)= 1.8×10^(-11)
Ksp(Mg(OH)2)= c(<Mg>2+)× [ c(<OH>-)] ^2
饱和溶液中 c(<OH>-)= c(<Mg>2+)× 2
所以
Ksp(Mg(OH)2)= c(<Mg>2+)× [ c(<OH>-)] ^2
= 1/2 × c(<OH>-)× [ c(<OH>-)] ^2
= 1/2 × [ c(<OH>-)] ^3
解得:[ c(<OH>-)] = (2 × Ksp )^(1/3)
= [ 2 × 1.8×10^(-11)]^(1/3)
= 7.11379 ×10^(-3)mol/L
室温时,c(<OH>-)× c(<H3O>+)= 10^(-14)
则 c(<H3O>+)= 10^(-14)/ c(<OH>-)
= 10^(-14)/ 7.11379 ×10^(-3)
= 1.4057211×10^(-10) mol/L
pH = - lg [ <H3O>+ ] = - lg [ 1.4057211×10^(-10) ] = 9.8521
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