求翻译英文文献 10
Asuccessfulapproachtomodifyingtheintrinsicpropertiesofpurecarbonisbydopingwithheteroa...
A successful approach to modifying the intrinsic properties of
pure carbon is by doping with heteroatoms, such as N, B, S, and
P.30 Doping carbons by N has been by far the most widely
investigated and yields a thriving class of N-doped carbon
materials with various applications, including Li-ion batteries.
30−34 In Li−S batteries, N-doped carbons have been
reported to exhibit improved conductivity and enhance the
activity of S.35,36 B, electron-deficient counterpart to N, is
another prospective dopant.37−39 On one hand, B-doped
carbon has higher conductivity than plain carbon, much like
that of N-doped carbon. On the other hand, in contrast to Ndoped
carbon, B dopant in the carbon framework is positively
polarized, leading to chemisorption with negatively charged
species.37 Thus, B-doped carbons are expected to attract
polysulfide anions, thereby alleviating the shuttle effect.
Herein, we gain an insight into the role of B dopant on S/C
cathode by using B-doped porous carbon (BPC) as the host
material for S. Our study shows that because of the synergy
between B, C, and S, doping with B remarkably improves the
conductivity of the crude porous carbon and alters its surface
properties to effectively trap the polysulfide anions. Therefore,
S/BPC cathode shows high capacity, stable cyclability, and
excellent rate capability. 展开
pure carbon is by doping with heteroatoms, such as N, B, S, and
P.30 Doping carbons by N has been by far the most widely
investigated and yields a thriving class of N-doped carbon
materials with various applications, including Li-ion batteries.
30−34 In Li−S batteries, N-doped carbons have been
reported to exhibit improved conductivity and enhance the
activity of S.35,36 B, electron-deficient counterpart to N, is
another prospective dopant.37−39 On one hand, B-doped
carbon has higher conductivity than plain carbon, much like
that of N-doped carbon. On the other hand, in contrast to Ndoped
carbon, B dopant in the carbon framework is positively
polarized, leading to chemisorption with negatively charged
species.37 Thus, B-doped carbons are expected to attract
polysulfide anions, thereby alleviating the shuttle effect.
Herein, we gain an insight into the role of B dopant on S/C
cathode by using B-doped porous carbon (BPC) as the host
material for S. Our study shows that because of the synergy
between B, C, and S, doping with B remarkably improves the
conductivity of the crude porous carbon and alters its surface
properties to effectively trap the polysulfide anions. Therefore,
S/BPC cathode shows high capacity, stable cyclability, and
excellent rate capability. 展开
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修改的内在特性,一个成功的方法
纯碳掺杂的杂原子,如N,B,S,和
由N掺杂碳捕获了迄今为止最广泛
调查和产量的氮掺杂碳繁荣的类
各种应用的材料,包括锂离子电池。
30 34锂电池−−,氮掺杂碳已
据报道,表现出改善的导电性和提高
s.35,36 B的活性,缺电子的对应的N,是
另一个潜在的杂质。37−39一方面,掺硼
碳具有比纯碳较高的电导率,很像
,氮掺杂碳。另一方面,在对比ndoped
碳,B掺杂的碳框架正
极化,导致吸附带负电荷
species.37因此,掺硼碳有望吸引
多硫化物阴离子,从而减轻飞机的影响。
在这里,我们洞察B掺杂的S / C的作用
通过使用含硼多孔碳阴极(BPC)作为东道主
对于美国的研究表明,由于协同效应的材料
在B,C,S,B掺杂显著提高了
天然的多孔碳的导电性和改变其表面
性能有效圈闭聚阴离子。因此,
S / BPC阴极显示容量高,循环性能稳定,和
优良率能力。
纯碳掺杂的杂原子,如N,B,S,和
由N掺杂碳捕获了迄今为止最广泛
调查和产量的氮掺杂碳繁荣的类
各种应用的材料,包括锂离子电池。
30 34锂电池−−,氮掺杂碳已
据报道,表现出改善的导电性和提高
s.35,36 B的活性,缺电子的对应的N,是
另一个潜在的杂质。37−39一方面,掺硼
碳具有比纯碳较高的电导率,很像
,氮掺杂碳。另一方面,在对比ndoped
碳,B掺杂的碳框架正
极化,导致吸附带负电荷
species.37因此,掺硼碳有望吸引
多硫化物阴离子,从而减轻飞机的影响。
在这里,我们洞察B掺杂的S / C的作用
通过使用含硼多孔碳阴极(BPC)作为东道主
对于美国的研究表明,由于协同效应的材料
在B,C,S,B掺杂显著提高了
天然的多孔碳的导电性和改变其表面
性能有效圈闭聚阴离子。因此,
S / BPC阴极显示容量高,循环性能稳定,和
优良率能力。
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