(1)已知:Fe(s)+12O2(g)=FeO(s)△H=-272.0kJ?mol-12Al(s)+32O2(g)=Al2O3(s)△H=-1675.7kJ?
(1)已知:Fe(s)+12O2(g)=FeO(s)△H=-272.0kJ?mol-12Al(s)+32O2(g)=Al2O3(s)△H=-1675.7kJ?mol-1A...
(1)已知:Fe(s)+12O2(g)=FeO(s)△H=-272.0kJ?mol-12Al(s)+32O2(g)=Al2O3(s)△H=-1675.7kJ?mol-1Al和FeO发生铝热反应的热化学方程式是______.(2)由氢气和氧气反应生成1mol水蒸气放热241.8kJ,若1g水蒸气转化成液态水时放热2.444KJ,试写出氢气燃烧生成液态水的热化学方程式______.
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(1)①Fe(s)+
O2(g)═FeO(s)△H1=-272.0kJ?mol-1;
②2Al(s)+
O2(g)═Al2O3(s)△H2=-1675.7kJ?mol-1;
依据盖斯定律计算②-①×3得到:3FeO(s)+2Al(s)=Al2O3(s)+3Fe(s)△H=-859.7KJ/mol;
故答案为:3FeO(s)+2Al(s)=Al2O3(s)+3Fe(s)△H=-859.7kJ/mol.
(2)已知:①2H2(g)+O2(g)=2H2O(g)△H=-483.6kJ/mol;
②H2O(g)=H2O(l)△H=-(2.444×18)=-43.992kJ/mol,
则氢气和氧气反应生成液态水2H2(g)+O2(g)=H2O(l)的反应可以是①+②×2得到,所以此时△H=(-483.6kJ/mol)+2×4.992kJ/mol=-571.6kJ/mol,
故答案为:2H2(g)+O2(g)=2H2O(l)△H=-571.6kJ/mol.
1 |
2 |
②2Al(s)+
3 |
2 |
依据盖斯定律计算②-①×3得到:3FeO(s)+2Al(s)=Al2O3(s)+3Fe(s)△H=-859.7KJ/mol;
故答案为:3FeO(s)+2Al(s)=Al2O3(s)+3Fe(s)△H=-859.7kJ/mol.
(2)已知:①2H2(g)+O2(g)=2H2O(g)△H=-483.6kJ/mol;
②H2O(g)=H2O(l)△H=-(2.444×18)=-43.992kJ/mol,
则氢气和氧气反应生成液态水2H2(g)+O2(g)=H2O(l)的反应可以是①+②×2得到,所以此时△H=(-483.6kJ/mol)+2×4.992kJ/mol=-571.6kJ/mol,
故答案为:2H2(g)+O2(g)=2H2O(l)△H=-571.6kJ/mol.
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