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在20世纪初,物理学的研究发现,原先被共认为是电磁波的光,其实还具有微粒性。在光的波粒二象性的启发下,1926年德布罗意(deBroglie)利用逆向思维的方法提出了一个... 在20世纪初,物理学的研究发现,原先被共认为是电磁波的光,其实还具有微粒性。在光的波粒二象性的启发下,1926年德布罗意(de Broglie)利用逆向思维的方法提出了一个全新的假设:电子业具有波粒二象性,即具有静止质量的电子、原子等微观粒子,也应该具有波动性的特性,并预言微观粒子的波长λ、质量m和运动速率v关系如下:

我国化学家徐光宪根据原子轨道能量与主量子数n及角量子数l的相互关系,归纳得到一个(n+0.7l)的近似规律。他认为(n+0.7l)值越大,原子轨道能量越高。并把(n+0.7l)值得首位数相同的原子轨道归纳为一个能级组,如6s、4f、5d和6p轨道的(n+0.7l)值分别为6.0、6.1、6.4和6.7,因而都归为第六能级组。得出与鲍林近似能级图相同的能级分组结果。徐光宪还同时提出粒子外层电子的能量高低次序,可根据(n+0.4l)值来判断。例如,4s、3d轨道的(n+0.4l)值分别为4.0和3.8,及粒子中E4s〉E3d。故Mn2+粒子是由Mn原子失去4s2电子而得到的。较好的说明了原子总是失去最外层电子的客观规律。
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依然爱你丶宅男
2012-11-03
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In the early twentieth Century, the study of physics, which had previously been considered the electromagnetic wave is light, but also has a particulate.In the light of the wave two was inspired by the 1926, De Broglie (de Broglie) using the reverse way of thinking to put forward a new hypothesis: electronic industry has wave-particle two image, which has static quality electronic, atomic and other microscopic particles, should also has a fluctuation characteristic, and predicted that the microscopic particles the wavelength λ m, quality and rate of movement of V relationships are as follows:
The chemist Xu Guangxian according to atomic orbital energy and the principal quantum number N and angular quantum number L relations, summed to obtain a (n+0.7l) approximate rule.He thinks (n+0.7l) value is greater, the higher the atomic orbital energy.And (n+0.7l) is the first number of the same atomic orbital is reduced to a level groups, such as 6S, 4f, 5D and 6p orbit (n+0.7l) values were 6, 6.1, 6.4 and 6.7, which are classified as sixth level group.The Pauling approximation level map to the same level grouping results.Xu Guangxian also put forward at the same time particle outer electron energy level of the order, according to the (n+0.4l) value.For example, 4S, 3D orbit (n+0.4l) values were 4 and 3.8, and in E4s' E3d particles.The Mn2+ particle is composed of Mn atoms lose 4s2 electronics by.Better explains the atoms are always lose the outermost electron objective law.
在20世纪初,物理学的研究发现,原先被共认为是电磁波的光,其实还具有微粒性。在光的波粒二象性的启发下,1926年德布罗意(de Broglie)利用逆向思维的方法提出了一个全新的假设:电子业具有波粒二象性,即具有静止质量的电子、原子等微观粒子,也应该具有波动性的特性,并预言微观粒子的波长λ、质量m和运动速率v关系如下:

我国化学家徐光宪根据原子轨道能量与主量子数n及角量子数l的相互关系,归纳得到一个(n+0.7l)的近似规律。他认为(n+0.7l)值越大,原子轨道能量越高。并把(n+0.7l)值得首位数相同的原子轨道归纳为一个能级组,如6s、4f、5d和6p轨道的(n+0.7l)值分别为6.0、6.1、6.4和6.7,因而都归为第六能级组。得出与鲍林近似能级图相同的能级分组结果。徐光宪还同时提出粒子外层电子的能量高低次序,可根据(n+0.4l)值来判断。例如,4s、3d轨道的(n+0.4l)值分别为4.0和3.8,及粒子中E4s〉E3d。故Mn2+粒子是由Mn原子失去4s2电子而得到的。较好的说明了原子总是失去最外层电子的客观规律。
董琛安
2012-11-03 · 超过11用户采纳过TA的回答
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In the early twentieth Century, the study of physics, which had previously been considered the electromagnetic wave is light, but also has a particulate. In the light of the wave two was inspired by the 1926, De Broglie ( de Broglie ) using the reverse way of thinking to put forward a new hypothesis: electronic industry has wave-particle two image, which has static quality electronic, atomic and other microscopic particles, should also has a fluctuation characteristic, and predicted that the microscopic particles the wavelength λm, quality and rate of movement of V relationships are as follows:
The chemist Xu Guangxian according to atomic orbital energy and the principal quantum number N and angular quantum number L relations, summed to obtain a ( n+0.7l ) approximate rule. He thinks ( n+0.7l ) value is greater, the higher the atomic orbital energy. And (n+0.7l ) is the first number of the same atomic orbital is reduced to a level groups, such as 6S, 4f, 5D and 6p orbit ( n+0.7l ) values were 6, 6.1, 6.4 and 6.7, which are classified as sixth level group. The Pauling approximation level map to the same level grouping results. Xu Guangxian also put forward at the same time particle outer electron energy level of the order, according to the ( n+0.4l ) value. For example, 4S, 3D orbit ( n+0.4l ) values were 4 and 3.8, and in E4s ' E3d particles. The Mn2+ particle is composed of Mn atoms lose 4s2 electronics by. Better explains the atoms are always lose the outermost electron objective law.
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