有一段与电化学有关的英文文献,求中文翻译,不要软件的,给高悬赏

INTRODUCTIONThefunctionalcompositematerialshavebecomeanareaofactiveresearchasmaterial... INTRODUCTION
The functional composite materials have become
an area of active research as materials of new genera
tion in chemical technology. Among them, especially
promising materials are polymer composites in which
nanoparticles of metals (or their compounds) are
introduced into the porous matrix (base) with grafted
ionexchange sites. Nanocomposites (NCs) of this
type can promote many chemical processes because of
the high reactivity of nanosized particles that possess
excess energy [1–5].
It was reported [6, 7] that starting from a certain
critical content of the metal, its state is no longer a col
lection of isolated particles, but is an assembly of clus
ters in which a charge transfer is possible at an opti
mum distance between particles. This leads to a drastic
change in the rate of stages including the charge trans
fer and should therefore be taken into account. An
increase in the amount of the metal introduced in the
carrier should lead to increased rates of processes
involving NCs due to the increased capacity of one of
the system’s components and increased specific con
ductivity. On the other hand, an increase in the con
tents of metal particles can significantly affect the
transport properties of the ionexchange support and
block access to ionogen centers.
Therefore, it seems important to correlate the con
tent of metal particles in the ionexchange matrix with
the kinetic characteristics of the chemical reaction
involving them. This will allow us to assess the optimal
capacity of the metal component in the composite.
The aim of this work was to study the rate and
mechanism of the interaction of molecular oxygen
dissolved in water with copper–ion exchanger nano
composites depending on the metal component
capacity in them.
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alexjfq
2015-03-13 · TA获得超过4954个赞
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复合功能材料已经成为新一代化工材料研究领域的一个热点。在(众多)的复合功能材料中,高分子复合材料的前景最为广阔,它是将金属(或其化合物)纳米离子加入含有接枝离子交换晶格点的多孔基体中所形成的。由于高活性的纳米级离子含有多余的能量,故高分子复合材料能促进许多化学反应的进行。
据报道,自金属含量的一个临界值开始,高分子复合材料的状态将不再是一些独立离子的集合体,而是变成了簇组合体,电荷在其中可能会以最优距离进行转移。
V凯love
2015-03-12 · TA获得超过102个赞
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爱莫能助啊
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ir511
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