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标定:称取0.15克预先在105℃干燥至恒重的基准三氧化二砷,称准至0.0001克。置于碘量瓶中,加10毫升氢氧化钠滴定液(0.1mol/L)微热使溶解,加20毫升蒸馏水...
标定:称取0.15克预先在105℃干燥至恒重的基准三氧化二砷,称准至0.0001克。置于碘量瓶中,加10毫升氢氧化钠滴定液(0.1mol/L)微热使溶解,加20毫升蒸馏水,加1滴甲基橙指示液,用硫酸溶液(0.5mol/L)中和,使黄色转变为粉红色,加2克碳酸氢钠、50毫升水、2毫升淀粉指示液(5g/l),用配制好的碘溶液(0.1mol/L)滴定至溶液呈浅蓝色,同时做空白试验。
计算:C(1/2I2)=m/(V1-V2)×0.04946
m:三氧化二砷质量, g
V1:碘溶液之用量,毫升
V2:空白试验碘溶液之用量,毫升
0.04946:与1毫升碘标准溶液相当的以克表示的三氧化二砷的质量。
2. 2N硫酸溶液:
量取100毫升浓硫酸缓缓加入900毫升蒸馏水中,稀释至1000毫升。
3. 1%可溶性淀粉指示液:
取1.0克可溶性淀粉,加5毫升水使成糊状,在搅拌下将糊状物
加到90毫升沸腾的水中,煮沸1~2分钟,冷却稀释至100毫升,使用期为两周。 展开
计算:C(1/2I2)=m/(V1-V2)×0.04946
m:三氧化二砷质量, g
V1:碘溶液之用量,毫升
V2:空白试验碘溶液之用量,毫升
0.04946:与1毫升碘标准溶液相当的以克表示的三氧化二砷的质量。
2. 2N硫酸溶液:
量取100毫升浓硫酸缓缓加入900毫升蒸馏水中,稀释至1000毫升。
3. 1%可溶性淀粉指示液:
取1.0克可溶性淀粉,加5毫升水使成糊状,在搅拌下将糊状物
加到90毫升沸腾的水中,煮沸1~2分钟,冷却稀释至100毫升,使用期为两周。 展开
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Calibration: say take 0.15 g in 105 ℃ dry in advance to the heng zhong benchmark of arsenic trioxide, says accurate to 0.0001 grams. In LiangPing iodine, add 10 ml sodium hydroxide titration solution (0.1 mol/L) the heat to dissolve, add 20 ml of distilled water, add 1 drop methyl orange instructions liquid, with sulfuric acid solution (0.5 mol/L) and, yellow for pink, add 2 grams of sodium bicarbonate, 50 ml water, 2 ml of starch liquid instructions (5 g/L), with the preparation good iodine solution (0.1 mol/L) titration solution to a shallow blue, at the same time be blank test.
Computing: C (1/2 I2) = m / (V1-v2) x 0.04946
M: arsenic trioxide quality, g
V1: iodine solution of the dosage, ml
V2: blank test of iodine solution dosage, ml
0.04946: and 1 ml iodine standard solution is in grams of said arsenic trioxide quality.
2. 2 N sulfuric acid solution:
Take 100 ml of strong sulfuric acid slowly add in 900 ml of distilled water, dilute to 1000 ml.
3. 1% soluble starch liquid instructions:
Take 1.0 grams of soluble starch, add 5 ml water into paste, stir in the next will paste
Add to 90 ml of boiling water, boil 1 ~ 2 minutes, cooling dilution to 100 milliliters, life for two weeks.
Computing: C (1/2 I2) = m / (V1-v2) x 0.04946
M: arsenic trioxide quality, g
V1: iodine solution of the dosage, ml
V2: blank test of iodine solution dosage, ml
0.04946: and 1 ml iodine standard solution is in grams of said arsenic trioxide quality.
2. 2 N sulfuric acid solution:
Take 100 ml of strong sulfuric acid slowly add in 900 ml of distilled water, dilute to 1000 ml.
3. 1% soluble starch liquid instructions:
Take 1.0 grams of soluble starch, add 5 ml water into paste, stir in the next will paste
Add to 90 ml of boiling water, boil 1 ~ 2 minutes, cooling dilution to 100 milliliters, life for two weeks.
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Calibration:
Weigh 0.15 g of benchmark arsenic trioxide pre-dried at 105 ℃ to constant weight. When weigh it, accurate to 0.0001 grams. Put it in the iodine flask, add 10 ml sodium hydroxide titration solution (0.1 mol/L) make it lukewarm to dissolve. Add 20 ml of distilled water, add 1 drop methyl orange indicating liquid,and neutralize it with sulfuric acid solution (0.5 mol/L) , turn it from yellow to pink, add 2 grams of sodium bicarbonate, 50 ml water, 2 ml of starch
indicating liquid (5 g/L),titrate it with the prepared iodine solution (0.1 mol/L)to light blue,and at the same time conduct the blank test.
Computing: C (1/2 I2) = m / (V1-v2) x 0.04946
M: arsenic trioxide quality, g
V1: the dosage of iodine solution , ml
V2: the dosage ofiodine solution used in blank test , ml
0.04946: the mass of arsenic trioxide in grams equivalent to 1 ml iodine standard solution.
2. 2 N sulfuric acid solution:
Take 100 ml of strong sulfuric acid slowly add in 900 ml of distilled water, dilute to 1000 ml.
3. 1% soluble starch liquid instructions:
Take 1.0 grams of soluble starch, add 5 ml water to paste, stirring the paste,add it to 90 ml of boiling water ,boil it for 1 to 2 minutes, cool and dilute it to 100 ml, it can be used in two weeks.
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Weigh 0.15 g of benchmark arsenic trioxide pre-dried at 105 ℃ to constant weight. When weigh it, accurate to 0.0001 grams. Put it in the iodine flask, add 10 ml sodium hydroxide titration solution (0.1 mol/L) make it lukewarm to dissolve. Add 20 ml of distilled water, add 1 drop methyl orange indicating liquid,and neutralize it with sulfuric acid solution (0.5 mol/L) , turn it from yellow to pink, add 2 grams of sodium bicarbonate, 50 ml water, 2 ml of starch
indicating liquid (5 g/L),titrate it with the prepared iodine solution (0.1 mol/L)to light blue,and at the same time conduct the blank test.
Computing: C (1/2 I2) = m / (V1-v2) x 0.04946
M: arsenic trioxide quality, g
V1: the dosage of iodine solution , ml
V2: the dosage ofiodine solution used in blank test , ml
0.04946: the mass of arsenic trioxide in grams equivalent to 1 ml iodine standard solution.
2. 2 N sulfuric acid solution:
Take 100 ml of strong sulfuric acid slowly add in 900 ml of distilled water, dilute to 1000 ml.
3. 1% soluble starch liquid instructions:
Take 1.0 grams of soluble starch, add 5 ml water to paste, stirring the paste,add it to 90 ml of boiling water ,boil it for 1 to 2 minutes, cool and dilute it to 100 ml, it can be used in two weeks.
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Calibration: say take 0.15 g in 105 ℃ dry in advance to the heng zhong benchmark of arsenic trioxide, says accurate to 0.0001 grams. In LiangPing iodine, add 10 ml sodium hydroxide titration solution (0.1 mol/L) the heat to dissolve, add 20 ml of distilled water, add 1 drop methyl orange instructions liquid, with sulfuric acid solution (0.5 mol/L) and, yellow for pink, add 2 grams of sodium bicarbonate, 50 ml water, 2 ml of starch liquid instructions (5 g/L), with the preparation good iodine solution (0.1 mol/L) titration solution to a shallow blue, at the same time be blank test.
Computing: C (1/2 I2) = m / (V1-v2) x 0.04946
M: arsenic trioxide quality, g
V1: iodine solution of the dosage, ml
V2: blank test of iodine solution dosage, ml
0.04946: and 1 ml iodine standard solution is in grams of said arsenic trioxide quality.
2. 2 N sulfuric acid solution:
Computing: C (1/2 I2) = m / (V1-v2) x 0.04946
M: arsenic trioxide quality, g
V1: iodine solution of the dosage, ml
V2: blank test of iodine solution dosage, ml
0.04946: and 1 ml iodine standard solution is in grams of said arsenic trioxide quality.
2. 2 N sulfuric acid solution:
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不是自己翻译的吧???be blank test很坑爹的
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自己在字典上查的
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